Rational Design of Efficient Amine Reductant Initiators for Amine–Peroxide Redox Polymerization
نویسندگان
چکیده
منابع مشابه
Polysaccharides as initiators of nucleic acid polymerization
Quantum-chemical calculations and in vitro experiments have demonstrated that polysaccharides are able to adsorb mononucleotides due to the formation of hydrogen bonds. The subsequent dehydration of polysaccharide-nucleotide complexes in the physiologically acceptable temperature range results in the creation of “correct” DNA polymers that are “recognized” by the specific DNA-polymerases. DNA f...
متن کاملkinetics of waterborne alkyd/acrylic hybrid resin free radical polymerization by two systems of redox and thermal initiators
kinetics of radical polymerizations of waterborne alkyd/acrylic hybrid resin via batch mini-emulsion technique was studied using redox initiators (tbhp/fe2+/edta/asac and tbhp/fe2+/edta/sfs) at relatively low temperatures and thermal initiators (bpo, kps and aibn) at higher temperatures to seek the most suitable initiator system. at the end of all reactions the unreacted monomer content was r...
متن کاملFormation of epoxide-amine oligo-adducts as OH-functionalized initiators for the ring-opening polymerization of ε-caprolactone
Epoxide-amine oligo-adducts were synthesized via a one-pot microwave assisted heterogeneous catalytic transfer hydrogenation. Accordingly, 4-nitroanisole was reduced under microwave conditions to give 4-aminoanisole which reacted immediately with the diglycidyl ether of bisphenol A in an addition polymerization reaction to yield oligo(amino alcohol)s. The hydroxy groups of the new formed oligom...
متن کاملSpectromicroscopic insights for rational design of redox-based memristive devices
The demand for highly scalable, low-power devices for data storage and logic operations is strongly stimulating research into resistive switching as a novel concept for future non-volatile memory devices. To meet technological requirements, it is imperative to have a set of material design rules based on fundamental material physics, but deriving such rules is proving challenging. Here, we eluc...
متن کاملThe rational design of suicide substrates of amine oxidases.
Eidelberg, E., Baxter, C. F., Roberts, E. & Saldias, C. A. (1960) in Inhibition in the Nervous System and y-Aminobutyric Acid (Roberts, E., Baxter, C. F., Van Harreveld, A., Wiersma, C. A. G., Adey, W. R. & Killam, K. F., eds.), pp. 562-578, Pergamon Press, New York Fletcher, A. & Fowler, L. J. (1980) Biochem. Pharmacol. 29,145& 1459 Fletcher, A. & Fowler, L. J. (1982) J. Neurochem. 38, 1022-10...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Journal of the American Chemical Society
سال: 2019
ISSN: 0002-7863,1520-5126
DOI: 10.1021/jacs.8b13679